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- W2317883955 endingPage "6823" @default.
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- W2317883955 abstract "Extension-induced crystallization under near-equilibrium condition has been studied in a series of lightly cross-linked high density polyethylene (XL-HDPE) with a combination of extensional rheology and in situ synchrotron radiation small-angle X-ray scattering (SAXS) and wide-angle X-ray diffraction (WAXD) measurements. According to crystal morphology and structure, four regions were defined in strain-temperature space, namely “orthorhombic lamellar crystal” (OLC), “orthorhombic shish crystal” (OSC), “hexagonal shish crystal” (HSC) and “oriented shish precursor” (OSP), respectively. This indicates that flow not only induces entropic reduction of initial melt, but also modifies the free energies of the final states, which is overlooked in the classical stretched network model (SNM) for flow induced crystallization (FIC). Incorporating the free energies of various final states, a modified SNM is developed and employed to analyze strain-temperature equivalence on nucleation in FIC, which reveals that the critical nucleus thickness l* at different regions leads to a natural transition from lamellar to shish nuclei. The results suggest that classical nucleation theory is still valid for FIC under near-equilibrium condition provided that the free energy changes of initial melt and final states induced by flow are taken into account." @default.
- W2317883955 created "2016-06-24" @default.
- W2317883955 creator A5007695962 @default.
- W2317883955 creator A5015625878 @default.
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- W2317883955 creator A5044655974 @default.
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- W2317883955 creator A5065243271 @default.
- W2317883955 creator A5066564329 @default.
- W2317883955 creator A5074911294 @default.
- W2317883955 date "2014-09-24" @default.
- W2317883955 modified "2023-10-15" @default.
- W2317883955 title "Extension-Induced Nucleation under Near-Equilibrium Conditions: The Mechanism on the Transition from Point Nucleus to Shish" @default.
- W2317883955 cites W118931958 @default.
- W2317883955 cites W1964790819 @default.
- W2317883955 cites W1965202772 @default.
- W2317883955 cites W1965244030 @default.
- W2317883955 cites W1965909643 @default.
- W2317883955 cites W1974869220 @default.
- W2317883955 cites W1975641004 @default.
- W2317883955 cites W1976031861 @default.
- W2317883955 cites W1976940766 @default.
- W2317883955 cites W1980271609 @default.
- W2317883955 cites W1982732247 @default.
- W2317883955 cites W1983798838 @default.
- W2317883955 cites W1985127271 @default.
- W2317883955 cites W1985380207 @default.
- W2317883955 cites W1987601666 @default.
- W2317883955 cites W1990121978 @default.
- W2317883955 cites W1994483487 @default.
- W2317883955 cites W1998375175 @default.
- W2317883955 cites W1998653138 @default.
- W2317883955 cites W1999640266 @default.
- W2317883955 cites W2005314582 @default.
- W2317883955 cites W2006668037 @default.
- W2317883955 cites W2009801564 @default.
- W2317883955 cites W2012673525 @default.
- W2317883955 cites W2013101073 @default.
- W2317883955 cites W2014591084 @default.
- W2317883955 cites W2016286640 @default.
- W2317883955 cites W2017463402 @default.
- W2317883955 cites W2018065881 @default.
- W2317883955 cites W2019927397 @default.
- W2317883955 cites W2019952792 @default.
- W2317883955 cites W2022083194 @default.
- W2317883955 cites W2025497176 @default.
- W2317883955 cites W2029688102 @default.
- W2317883955 cites W2030019472 @default.
- W2317883955 cites W2031144384 @default.
- W2317883955 cites W2032279300 @default.
- W2317883955 cites W2032524008 @default.
- W2317883955 cites W2032557389 @default.
- W2317883955 cites W2033002712 @default.
- W2317883955 cites W2034645292 @default.
- W2317883955 cites W2036809892 @default.
- W2317883955 cites W2040388377 @default.
- W2317883955 cites W2040643460 @default.
- W2317883955 cites W2046506173 @default.
- W2317883955 cites W2048516380 @default.
- W2317883955 cites W2048998367 @default.
- W2317883955 cites W2054129389 @default.
- W2317883955 cites W2058973428 @default.
- W2317883955 cites W2059309085 @default.
- W2317883955 cites W2066279009 @default.
- W2317883955 cites W2068785709 @default.
- W2317883955 cites W2069409125 @default.
- W2317883955 cites W2069658542 @default.
- W2317883955 cites W2069860202 @default.
- W2317883955 cites W2073487173 @default.
- W2317883955 cites W2073774194 @default.
- W2317883955 cites W2074366690 @default.
- W2317883955 cites W2075645935 @default.
- W2317883955 cites W2076626795 @default.
- W2317883955 cites W2079140733 @default.
- W2317883955 cites W2080212588 @default.
- W2317883955 cites W2081324328 @default.
- W2317883955 cites W2087669313 @default.
- W2317883955 cites W2088533028 @default.
- W2317883955 cites W2090654376 @default.
- W2317883955 cites W2096379884 @default.
- W2317883955 cites W2106735376 @default.
- W2317883955 cites W2108581225 @default.
- W2317883955 cites W2109926164 @default.
- W2317883955 cites W2114404848 @default.
- W2317883955 cites W2118113802 @default.
- W2317883955 cites W2129531228 @default.
- W2317883955 cites W2131486141 @default.
- W2317883955 cites W2136700033 @default.
- W2317883955 cites W2143232781 @default.
- W2317883955 cites W2146996718 @default.
- W2317883955 cites W2147486950 @default.
- W2317883955 cites W2148849027 @default.
- W2317883955 cites W2170586247 @default.
- W2317883955 cites W2192841728 @default.
- W2317883955 cites W2317744712 @default.
- W2317883955 cites W2322720880 @default.
- W2317883955 cites W2322889108 @default.