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- W2317884195 abstract "The most unusual feature in the surface-enhanced Raman scattering (SERS) of 4-aminobenzenethiol (4-ABT) is the appearance of b2-type bands in the region of 1100–1500 cm–1, which, in recent years, has given rise to a dispute over their origin. In order to resolve this dispute, we have examined the SERS spectral pattern of 4-ABT derivatives adsorbed on Ag substrates. At first, we found in the SERS spectra of 4-(diethylamino)benzenethiol and 4-(benzylideneamino)benzenethiol that no photoreaction had taken place at all, but the b2-type bands appeared distinctly as is usual in the SERS of 4-ABT. The b2-type bands were also observed in the SERS spectra of other 4-ABT derivatives while, to our surprise, no such b2-type bands were observed at all in the SERS spectra of para-substituted (but not amino) benzenethiol derivatives. The appearance of the b2-type bands in the SERS spectra seemed thus a common feature of 4-ABT derivatives. The difference between 4-ABT derivatives and para-substituted (but not amino) benz..." @default.
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- W2317884195 date "2011-11-30" @default.
- W2317884195 modified "2023-10-17" @default.
- W2317884195 title "Surface-Enhanced Raman Scattering Characteristics of 4-Aminobenzenethiol Derivatives Adsorbed on Silver" @default.
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- W2317884195 doi "https://doi.org/10.1021/jp208945s" @default.
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