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- W2317893419 abstract "ZnS films were deposited by the pulse plating technique at different duty cycles in the range of 6 - 50 % and at a constant current density of 10 mA cm -2 .. The films exhibited single phase hexagonal ZnS. The grain size increased with decrease of duty cycle. Optical band gap of the films increased from 3.83 - 4.01 eV with increase of duty cycle. Optical constants (refractive index, n, extinction co-efficient, k, dielectric constant) of the films were obtained in the wavelength range 300-1850 nm by using spectrophotometric measurement. The obtained results concerning the absorption index yield the energy gap in addition to the type of the allowed optical transitions. N/m* ratio has been obtained from refractive index data. The dispersion of refractive index is analyzed by using a single oscillator model. Zinc sulfide (ZnS) is found in nature as zinc-blende (also called sphalerite or β-ZnS and with a cubic structure) and wurtzite (α-ZnS, which is a hexagonal structure). The names of these minerals are used to designate the corresponding crystalstructures. It is a II-VI compound semiconductor material and is commercially used in solar cells (3), infrared windows (4), and phosphor materials by doping with transition or rare-earth metals (5,6). There has been growing interest in developing techniques to prepare semiconductor ZnS thin films. ZnS thin films are produced using various techniques, including radio frequency (RF) magnetron sputtering (7), chemical vapor deposition (CVD) (8), solvothermal (9) and chemical bath deposition (10). In an earlier paper, details of pulse plating technique at different duty cycles in the range of 20 - 60 % and the structural, morphological and band gap of the films were reported (11). In this work, we report on the deposition of ZnS thin films at different duty cycles in the range of 6 - 50 %, using pulse electrodeposition technique. Optical properties of the films are analyzed and the optical constants were evaluated and discussed. In pulse electrodeposition (12,13) the potential or current is alternated swiftly between two different values. This results in a series of pulses of equal amplitude, duration and polarity, separated by zero current. Each pulse consists of an ON-time (TON) during which potential and/current is applied, and an OFF-time (TOFF) during which zero current is applied. It is possible to control the deposited film composition and thickness in an atomic order by regulating the pulse amplitude and width. They favor the initiation of grain nuclei and greatly increase the number of grains per unit area resulting in finer grained deposit with better properties than conventionally plated coatings. The sum of the ON and OFF times constitute one pulse cycle. The duty cycle is" @default.
- W2317893419 created "2016-06-24" @default.
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- W2317893419 date "2014-01-01" @default.
- W2317893419 modified "2023-10-18" @default.
- W2317893419 title "Optical properties of pulse electrodeposited ZnS films" @default.
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- W2317893419 doi "https://doi.org/10.9790/4861-06320914" @default.
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