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• W2317942014 endingPage "581" @default.
• W2317942014 startingPage "568" @default.
• W2317942014 abstract "Rhodamine–bromonaphthaleneimide (RB–NI) and rhodamine–bromonaphthalenediimide (RB–NDI) dyads were prepared for switching of the triplet excited states. Bromo-NI or bromo-NDI parts in the dyads are the spin converters, i.e., the triplet state producing modules, whereas the RB unit is the acid-activatable electron donor/energy acceptor. NI and NDI absorb at 359 and 541 nm, and the T1 state energy levels are 2.25 and 1.64 eV, respectively. RB undertakes the reversible spirolactam (RB-c) ↔ opened amide (RB-o) transformation. RB-c shows no visible light absorption, and the triplet-state energy level is ET1 = 3.36 eV. Conversely RB-o shows strong absorption at 557 nm, and ET1 is 1.73 eV. Thus, the acid-activated fluorescence-resonance-energy-transfer (FRET) competes with the ISC of NI or NDI. No triplet state was observed for the dyads with nanosecond time-resolved transient absorption spectroscopy. Upon addition of acid, strong fluorescence and long-living triplet excited states were observed. Thus, the producing of triplet state is acid-activatable. The triplet state of RB–NI is localized on RB-o part, whereas in RB–NDI the triplet state is delocalized on both the NDI and RB-o units. The ISC of spin converter was not outcompeted by RET. These studies are useful for switching of triplet excited state." @default.
• W2317942014 created "2016-06-24" @default.
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• W2317942014 creator A5081126599 @default.
• W2317942014 creator A5087197441 @default.
• W2317942014 date "2014-12-16" @default.
• W2317942014 modified "2023-10-18" @default.
• W2317942014 title "Switching of the Triplet Excited State of Rhodamine/Naphthaleneimide Dyads: An Experimental and Theoretical Study" @default.
• W2317942014 cites W1964306662 @default.
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• W2317942014 cites W1977183685 @default.
• W2317942014 cites W1983856894 @default.
• W2317942014 cites W1985802355 @default.
• W2317942014 cites W1989720103 @default.
• W2317942014 cites W1990412045 @default.
• W2317942014 cites W1991213559 @default.
• W2317942014 cites W1991318003 @default.
• W2317942014 cites W1996183495 @default.
• W2317942014 cites W2001057125 @default.
• W2317942014 cites W2001443197 @default.
• W2317942014 cites W2001597292 @default.
• W2317942014 cites W2006459597 @default.
• W2317942014 cites W2012078348 @default.
• W2317942014 cites W2012848498 @default.
• W2317942014 cites W2013776182 @default.
• W2317942014 cites W2020085371 @default.
• W2317942014 cites W2025099464 @default.
• W2317942014 cites W2025143931 @default.
• W2317942014 cites W2027326776 @default.
• W2317942014 cites W2034233659 @default.
• W2317942014 cites W2035152299 @default.
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• W2317942014 cites W2040566683 @default.
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• W2317942014 cites W2082299249 @default.
• W2317942014 cites W2084343235 @default.
• W2317942014 cites W2090936867 @default.
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• W2317942014 cites W2116466989 @default.
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• W2317942014 doi "https://doi.org/10.1021/jo502554y" @default.
• W2317942014 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/25436874" @default.
• W2317942014 hasPublicationYear "2014" @default.
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