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• W2317960009 abstract "We report the synthesis and single-crystal molecular structures of two stereoisomers of trigonal-bipyramidal hydrido dicarbonyl Ir complexes [(L2)Ir(H)(CO)2] with ae (axial–equatorial) and ee (equatorial–equatorial) ligand P coordination and fluxional behavior in solution. L2 is a new chelating bisphosphite with unprecedented high selectivity in Rh-catalyzed bis-hydroformylation of butadiene to adipic aldehyde. These Ir analogues are ideal stabilized structural models for nonseparable ae and ee Rh-hydroformylation resting state isomers [(L2)Rh(H)(CO)2]. With Ir, both stereoisomers with the same ligand could be characterized independently for the first time." @default.
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• W2317960009 date "2014-06-05" @default.
• W2317960009 modified "2023-10-12" @default.
• W2317960009 title "Iridium Models of Rhodium Intermediates in Hydroformylation Catalysis: Isolation and Molecular Structures of Fluxional ae and ee Isomers" @default.
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• W2317960009 doi "https://doi.org/10.1021/om401139u" @default.
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