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• W2317966420 abstract "Density functional theory (DFT; OLYP) calculations clearly indicate the involvement of a cobalt nitrene in cobalt-porphyrin–catalyzed alkene aziridinations, as well as in allylic aminations. The transition state for the cobalt-nitrene–alkene interaction may be described as triradicaloid. A subsequent carbon radical, if it exists at all as an intermediate, collapses in an essentially barrierless manner to the aziridine product." @default.
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• W2317966420 date "2011-04-29" @default.
• W2317966420 modified "2023-10-16" @default.
• W2317966420 title "Mechanism of Cobalt-Porphyrin–Catalyzed Aziridination" @default.
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• W2317966420 doi "https://doi.org/10.1021/cs1001114" @default.
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