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- W2318053400 abstract "By using 13C solid-state NMR spectroscopy and GC-MS analysis, the activation of methane and coaromatization of methane and propane have been monitored on gallium-modified zeolite BEA at 573−823 K. A noticeable degree involvement of the 13C-label from methane-13C into the aromatic reaction products (benzene, toluene) has been demonstrated. The major intermediate of the methane activation represents gallium-methyl species, which are formed by methane dissociative adsorption on Ga2O3 species of the zeolite. The minor species of methane activation, Ga-methoxy groups, provide the involvement of methane into aromatics by the methylation of aromatic molecules, which are generated exclusively from propane, by the mechanism of electrophilic substitution. Ga-methyl species can serve as methylating nucleophilic agent for the reaction of nucleophilic substitution with participation of aromatic molecules, which contain the electron-withdrawing substitutes." @default.
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- W2318053400 date "2010-11-11" @default.
- W2318053400 modified "2023-10-10" @default.
- W2318053400 title "The “Alkyl” and “Carbenium” Pathways of Methane Activation on Ga-Modified Zeolite BEA: <sup>13</sup>C Solid-State NMR and GC-MS Study of Methane Aromatization in the Presence of Higher Alkane" @default.
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- W2318053400 doi "https://doi.org/10.1021/jp1078899" @default.
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