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- W2318058429 abstract "The TiCl4 induced anomerization of selenium glycosides of galacturonic acid derivatives is reported. The reaction was successful for galacturonic acid when various alkyl, alkenyl, alkynyl, saccharide, steroid, and lipid groups were attached to the anomeric Se atom. An increased amount of TiCl4 and/or higher temperature were needed to ensure completion of the reaction in some cases. Yields were higher for reactions carried out at higher dilution. The reaction was applied to the synthesis of Se-based mimics of the potent immunostimulant α-GalCer (KRN7000)." @default.
- W2318058429 created "2016-06-24" @default.
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- W2318058429 date "2016-01-22" @default.
- W2318058429 modified "2023-10-14" @default.
- W2318058429 title "Lewis Acid Induced Anomerization of <i>Se</i>-Glycosides. Application to Synthesis of α-<i>Se</i>-GalCer" @default.
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- W2318058429 doi "https://doi.org/10.1021/acs.orglett.5b03591" @default.
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