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• W2318078947 endingPage "18097" @default.
• W2318078947 startingPage "18087" @default.
• W2318078947 abstract "Novel dendronized silica substrates were synthesized. First- and second- generation polyaryl ether dendrons were appended to silica surfaces. Using Cu(I) mediated cycloaddition click chemistry, β-cyclodextrin was tethered to the dendronized surfaces and to a nondendronized surface for comparison purposes. This synthesis strategy affords a modular, versatile method for surface functionalization in which the density of functional groups can be readily varied by changing the generation of dendron used. The surfaces, which are capable of adsorbing target analytes, have been characterized and studied using X-ray photoelectron spectroscopy (XPS) and vibrational sum frequency spectroscopy (VSFS). Fluorescence spectroscopy was used to study the surfaces' ability to retain coumarin 152 (C152). These studies indicated that the β-cyclodextrin functionalized surfaces not only adsorbed C152 but also retained it through multiple aqueous washes. Furthermore, these observations were quantified and show that substrates functionalized with first-generation dendrons have a more than 6 times greater capacity to adsorb C152 than slides functionalized with monomeric β-cyclodextrin. The first-generation dendrons also have 2 times greater the capacity than the larger generation dendrons. This result is explained by describing a dendron that has an increased number of β-cyclodextrin monomers but, when covalently bound to silica, has a footprint too large to optimize the number of accessible monomers. Overall, both dendronized surfaces demonstrated an increased capacity to adsorb targeted analytes over the slides functionalized with monomeric β-cyclodextrin. The studies reported provide a methodology for characterizing and evaluating the properties of novel, highly functional surfaces." @default.
• W2318078947 created "2016-06-24" @default.
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• W2318078947 date "2014-10-13" @default.
• W2318078947 modified "2023-10-05" @default.
• W2318078947 title "Cyclodextrin-Functionalized Chromatographic Materials Tailored for Reversible Adsorption" @default.
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• W2318078947 doi "https://doi.org/10.1021/am504975y" @default.
• W2318078947 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/25249268" @default.
• W2318078947 hasPublicationYear "2014" @default.
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