Matches in SemOpenAlex for { <https://semopenalex.org/work/W2318152601> ?p ?o ?g. }
- W2318152601 endingPage "1020" @default.
- W2318152601 startingPage "1013" @default.
- W2318152601 abstract "New amido- and alkoxo-bridged dinuclear cobalt complexes [Cp*Co(μ-X)]2 (X = NHTol (2), NHBoc (3), OBn (4); Cp* = η5-C5Me5; Tol = p-tolyl; Boc = t-BuOCO; Bn = CH2Ph) have been prepared by the reaction of [Cp*Co(μ-Cl)]2 (1) with LiX and characterized by X-ray analysis. The amido complexes 2 and 3 are diamagnetic and feature a folded Co2N2 butterfly structure with a Co−Co single bond. In contrast, the alkoxo complex 4 is paramagnetic and contains a planar Co2O2 core with a long Co···Co separation. Dynamic stereochemical processes in 2 and 3 were investigated by NMR spectroscopy, and cis−trans isomerization in 2 and Co2N2 ring inversion in 2 and 3 were identified. Complexes 2 and 4 reacted with carbon monoxide to give N,N′-di-p-tolylurea and dibenzyl carbonate, respectively, along with [Cp*Co(CO)2] and [Cp*Co(μ-CO)]2. Oxidation of 2 with iodine and ferrocenium triflate afforded the Co(III) complexes [(Cp*Co)2(μ-I)(μ-NHTol)2]I (5) and [(Cp*Co)2(μ-OH2)(μ-NHTol)2][OTf]2 (6), respectively, the latter being characterized by X-ray analysis." @default.
- W2318152601 created "2016-06-24" @default.
- W2318152601 creator A5008569899 @default.
- W2318152601 creator A5044407607 @default.
- W2318152601 creator A5089380907 @default.
- W2318152601 date "2011-02-08" @default.
- W2318152601 modified "2023-10-08" @default.
- W2318152601 title "Dinuclear Cp*Co Amido and Alkoxo Complexes: Synthesis, Structures, and Reactivity" @default.
- W2318152601 cites W1557373297 @default.
- W2318152601 cites W1964069488 @default.
- W2318152601 cites W1965823295 @default.
- W2318152601 cites W1968763777 @default.
- W2318152601 cites W1971425837 @default.
- W2318152601 cites W1973420310 @default.
- W2318152601 cites W1974289997 @default.
- W2318152601 cites W1975918639 @default.
- W2318152601 cites W1978054929 @default.
- W2318152601 cites W1978683745 @default.
- W2318152601 cites W1979157854 @default.
- W2318152601 cites W1980115181 @default.
- W2318152601 cites W1980647783 @default.
- W2318152601 cites W1984086609 @default.
- W2318152601 cites W1985685745 @default.
- W2318152601 cites W1985857706 @default.
- W2318152601 cites W1986275488 @default.
- W2318152601 cites W1989031399 @default.
- W2318152601 cites W1989803343 @default.
- W2318152601 cites W1994153309 @default.
- W2318152601 cites W1994753638 @default.
- W2318152601 cites W1996247487 @default.
- W2318152601 cites W1997740585 @default.
- W2318152601 cites W1999856124 @default.
- W2318152601 cites W2001352066 @default.
- W2318152601 cites W2001471935 @default.
- W2318152601 cites W2002819914 @default.
- W2318152601 cites W2002858366 @default.
- W2318152601 cites W2008426787 @default.
- W2318152601 cites W2011814830 @default.
- W2318152601 cites W2013720916 @default.
- W2318152601 cites W2020172151 @default.
- W2318152601 cites W2021580078 @default.
- W2318152601 cites W2021846445 @default.
- W2318152601 cites W2024233826 @default.
- W2318152601 cites W2027423953 @default.
- W2318152601 cites W2027679321 @default.
- W2318152601 cites W2027868865 @default.
- W2318152601 cites W2028424679 @default.
- W2318152601 cites W2033076185 @default.
- W2318152601 cites W2033819232 @default.
- W2318152601 cites W2036753712 @default.
- W2318152601 cites W2042017900 @default.
- W2318152601 cites W2045896850 @default.
- W2318152601 cites W2052580583 @default.
- W2318152601 cites W2052997172 @default.
- W2318152601 cites W2054106667 @default.
- W2318152601 cites W2059020082 @default.
- W2318152601 cites W2060647782 @default.
- W2318152601 cites W2061437027 @default.
- W2318152601 cites W2064220438 @default.
- W2318152601 cites W2065399312 @default.
- W2318152601 cites W2067825164 @default.
- W2318152601 cites W2068400203 @default.
- W2318152601 cites W2075114791 @default.
- W2318152601 cites W2076132823 @default.
- W2318152601 cites W2077187637 @default.
- W2318152601 cites W2079326181 @default.
- W2318152601 cites W2081416805 @default.
- W2318152601 cites W2081813802 @default.
- W2318152601 cites W2089655596 @default.
- W2318152601 cites W2092240706 @default.
- W2318152601 cites W2093134996 @default.
- W2318152601 cites W2149972019 @default.
- W2318152601 cites W2156028148 @default.
- W2318152601 cites W2479050874 @default.
- W2318152601 cites W2490548268 @default.
- W2318152601 cites W2952684558 @default.
- W2318152601 doi "https://doi.org/10.1021/om101065z" @default.
- W2318152601 hasPublicationYear "2011" @default.
- W2318152601 type Work @default.
- W2318152601 sameAs 2318152601 @default.
- W2318152601 citedByCount "4" @default.
- W2318152601 countsByYear W23181526012014 @default.
- W2318152601 countsByYear W23181526012017 @default.
- W2318152601 countsByYear W23181526012022 @default.
- W2318152601 crossrefType "journal-article" @default.
- W2318152601 hasAuthorship W2318152601A5008569899 @default.
- W2318152601 hasAuthorship W2318152601A5044407607 @default.
- W2318152601 hasAuthorship W2318152601A5089380907 @default.
- W2318152601 hasConcept C121332964 @default.
- W2318152601 hasConcept C124712363 @default.
- W2318152601 hasConcept C126661725 @default.
- W2318152601 hasConcept C142724271 @default.
- W2318152601 hasConcept C155647269 @default.
- W2318152601 hasConcept C161790260 @default.
- W2318152601 hasConcept C178790620 @default.
- W2318152601 hasConcept C179104552 @default.
- W2318152601 hasConcept C185592680 @default.
- W2318152601 hasConcept C204787440 @default.