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• W2318191539 endingPage "4571" @default.
• W2318191539 startingPage "4563" @default.
• W2318191539 abstract "A detailed structural analysis of the antiferromagnetic (Gz-type) lanthanum doped bismuth ferrite - Bi0.5La0.5FeO3 (Pn′ma′) – using variable-temperature powder neutron diffraction is reported. The analysis highlights a structural link between changes in the relative dielectric permittivity and changes in the FeO6 octahedral tilt magnitudes, accompanied by a structural distortion of the octahedra with corresponding A-site displacement along the c-axis; this behavior is unusual due to an increasing in-phase tilt mode with increasing temperature. The anomalous orthorhombic distortion is driven by magnetostriction at the onset of antiferromagnetic ordering resulting in an Invar effect along the magnetic c-axis and anisotropic displacement of the A-site Bi3+ and La3+ along the a-axis." @default.
• W2318191539 created "2016-06-24" @default.
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• W2318191539 date "2012-11-16" @default.
• W2318191539 modified "2023-09-28" @default.
• W2318191539 title "Magnetically Driven Dielectric and Structural Behavior in Bi_0.5La_0.5FeO₃" @default.
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• W2318191539 doi "https://doi.org/10.1021/cm302513q" @default.
• W2318191539 hasPublicationYear "2012" @default.
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