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- W2318249529 abstract "Abstract The experimental result, that the equilibrium force is nearly equal to the pseudoequilibrium force immediately prior to quenching and irradiation, allows the following conclusions: (1) Chain scission during crosslinking is not a serious problem. (2) The network of highly entangled linear chains is effectively at elastic equilibrium immediately prior to crosslinking in the strained state. This would not be the case if the entangled structure remained untrapped. (3) The effect of chain entangling in tightly crosslinked elastomers is large, also at elastic equilibrium. In fact, it is almost quantitatively equal to the pseudo-equilibrium stress relaxation modulus of the uncrosslinked linear polymer. This result is in agreement with the results from the Langley and the two-network methods." @default.
- W2318249529 created "2016-06-24" @default.
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- W2318249529 date "1982-03-01" @default.
- W2318249529 modified "2023-10-18" @default.
- W2318249529 title "A Direct Experimental Determination of the Elastic Contribution of Chain Entangling in a Tightly Crosslinked Elastomer" @default.
- W2318249529 doi "https://doi.org/10.5254/1.3535875" @default.
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