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- W2318371070 abstract "The diffusion of dilute metallic lithium across the surface and into the bulk of atomically clean highly oriented pyrolytic graphite in ultrahigh vacuum is reported. Auger electron spectroscopy and a surface-dependent chemical reaction were utilized to monitor the coverage, oxidation state, and diffusion of Li. A very small diffusion activation energy (0.16 ± 0.02 eV; 15.4 ± 1.8 kJ/mol) is found for Li surface diffusion across the graphite basal plane. A model involving diffusion-rate-limited Li atom transport across the basal plane of graphite through step edge sites into the interior is proposed. These measurements indicate that the diffusion coefficient, D, for Li is very large (D(300 K) ≈ 5 × 10–6 cm2 s–1)." @default.
- W2318371070 created "2016-06-24" @default.
- W2318371070 creator A5006318899 @default.
- W2318371070 creator A5061083189 @default.
- W2318371070 date "2012-11-13" @default.
- W2318371070 modified "2023-09-30" @default.
- W2318371070 title "Rapid Atomic Li Surface Diffusion and Intercalation on Graphite: A Surface Science Study" @default.
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- W2318371070 doi "https://doi.org/10.1021/jp308101c" @default.
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