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- W2318373562 abstract "Reaction of BiX3 (X = Cl, Br, I) with [PtMe2(P–P)], (1a, P–P = dppm; 1b, P–P = dppe), occurs easily to yield a mixture of platinum(II) complexes [PtMeX(P–P)], 2, and [PtX2(P–P)], 3, and the binuclear complex [Pt2Me2(μ-X)(μ-dppm)2]X, 4. On the basis of 31P NMR and UV–vis spectroscopy, a mechanism is proposed in which the rate determining step is conversion of the yellowish Pt(II)-BiX3 adduct BiI3·[PtMe2(dppm)], A, into the Pt(IV)–Bi(III) intermediate [PtMe2(BiX2)X(P–P)], IM1. Density functional theory (DFT) studies suggest that intermediate IM1 may be formed in acetone solution which undergoes the Bi–C reductive elimination process before formation of complexes 2 and 3. The structures of intermediates IM1 were theoretically determined using DFT calculations. In dilute acetone solution, as monitored by UV–vis spectroscopy, the oxidative addition processes follow first order kinetics. The overall reaction is slower for heavier halide." @default.
- W2318373562 created "2016-06-24" @default.
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- W2318373562 date "2013-11-15" @default.
- W2318373562 modified "2023-10-16" @default.
- W2318373562 title "Bismuth–Halide Oxidative Addition and Bismuth–Carbon Reductive Elimination in Platinum Complexes Containing Chelating Diphosphine Ligands" @default.
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- W2318373562 doi "https://doi.org/10.1021/ic4018745" @default.
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