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- W2318399771 abstract "We demonstrate the concept that highly colored imidazolium porphyrazine ligands and complexes may be useful for visualizing the location of a catalyst and/or ligand. This was analytically demonstrated by the application of UV–vis spectrophotometry to detect the ligand and ICP-OES spectroscopy for quantification of the Pd in the biphasic systems. In the first instance, a toluene/water system was used, in which the complex and ligand preferred the organic phase. Water-soluble substrates were made to react under these conditions by employing the complexes as catalysts in Heck and Suzuki C–C bond forming reactions. In the second instance, an ionic liquid containing biphasic mixture was used, in which the ligand/catalyst was retained in the ionic liquid. Catalyst recycling experiments were met with limited success." @default.
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- W2318399771 date "2014-12-01" @default.
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- W2318399771 title "Color-Coded Ligands: Tracking the Catalyst using Highly Pigmented Porphyrazine Ligands in Biphasic Reactions" @default.
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- W2318399771 doi "https://doi.org/10.1021/om501094p" @default.
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