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• W2318477323 abstract "We report the first total synthesis of the complex akuammiline alkaloid picrinine, which was first isolated nearly five decades ago. Our synthetic approach features a concise assembly of the [3.3.1]-azabicyclic core, a key Fischer indolization reaction to forge the natural product’s carbon framework, and a series of delicate late-stage transformations to complete the synthesis. Our synthesis of picrinine also constitutes a formal synthesis of the related polycyclic alkaloid strictamine." @default.
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• W2318477323 date "2014-03-12" @default.
• W2318477323 modified "2023-10-12" @default.
• W2318477323 title "Total Synthesis of the Akuammiline Alkaloid Picrinine" @default.
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• W2318477323 doi "https://doi.org/10.1021/ja501780w" @default.
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