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• W2318478407 abstract "Ligands containing linked dipicolylamine (dpa) and bipyridine sites have been explored as platforms for the synthesis of heterometallic complexes containing the paramagnetic metals Cu(2+) and Co(2+). IR and EPR studies on the bimetallic complexes and simplified model compounds support dpa-selective binding by both of these metals. The IR spectra have also been compared to those of diamagnetic Rh(+), Zn(2+), and Pd(2+) complexes whose metal binding sites had been independently determined through NMR techniques. The binding preferences have been used to control selective metalation in the synthesis of heterometallic Pt/Cu, Pd/Cu, and Rh/Cu complexes." @default.
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• W2318478407 date "2013-11-21" @default.
• W2318478407 modified "2023-09-27" @default.
• W2318478407 title "Heterobimetallic Complexes of Polypyridyl Ligands Containing Paramagnetic Centers: Synthesis and Characterization by IR and EPR" @default.
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• W2318478407 doi "https://doi.org/10.1021/ic401952s" @default.
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