FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2318496742> ?p ?o ?g. }

• W2318496742 endingPage "281" @default.
• W2318496742 startingPage "274" @default.
• W2318496742 abstract "trans-Cyclooctanediyl-bridged [OSSO]-type ligand 4 reacts with TiCl4(thf)2 in toluene to produce the corresponding titanium(IV) dichloro complexes as an inseparable mixture of cis-α isomer 6a and cis-β isomer 6b in a ratio of 2:1, whereas treatment of dilithio salt of 4 with TiCl3(thf)3 in Et2O afforded chloride-bridged dimeric titanium(III) complex 8, which indicated the antiferromagnetic character in a nonpolar solvent solution. Di(isopropoxy) titanium(IV) complex 10 having a C2-symmetric cis-α configuration was synthesized by the reaction of 4 with Ti(OiPr)4 in toluene as yellow crystals. Moreover, the reaction of 4 with Ti(NEt2)4 in toluene resulted in the unexpected formation of [OSSO]-type bis(phenolato)-bridged dinuclear diamido titanium(IV) complex 11, which adopted a distorted tetrahedral geometry on the titanium center. These titanium complexes were characterized on the basis of their NMR spectroscopic data, and the molecular structures of complexes 8, 10, and 11 were established by single crystal X-ray diffraction. The titanium(IV) and (III) complexes 6 and 8 upon activation with a cocatalyst in toluene polymerized 1-hexene isospecifically to produce poly(1-hexene) having high molecular weight (Mw = 22,000–52,000 g mol–1) and relatively narrow polydispersity (Mw/Mn = 1.7–1.8), albeit with low activity [0.27–1.0 g mmol(cat)−1 h–1]." @default.
• W2318496742 created "2016-06-24" @default.
• W2318496742 creator A5010155058 @default.
• W2318496742 creator A5034447235 @default.
• W2318496742 creator A5045054303 @default.
• W2318496742 creator A5061347192 @default.
• W2318496742 date "2011-11-30" @default.
• W2318496742 modified "2023-09-28" @default.
• W2318496742 title "Titanium Complexes Supported by an [OSSO]-Type Bis(phenolato) Ligand Based on a <i>trans</i>-Cyclooctanediyl Platform: Synthesis, Structures, and 1-Hexene Polymerization" @default.
• W2318496742 cites W1963779283 @default.
• W2318496742 cites W1964147665 @default.
• W2318496742 cites W1969336176 @default.
• W2318496742 cites W1970233056 @default.
• W2318496742 cites W1973874721 @default.
• W2318496742 cites W1980353253 @default.
• W2318496742 cites W1988164835 @default.
• W2318496742 cites W1988276397 @default.
• W2318496742 cites W1990932567 @default.
• W2318496742 cites W1992658327 @default.
• W2318496742 cites W1994904151 @default.
• W2318496742 cites W2008234280 @default.
• W2318496742 cites W2016813855 @default.
• W2318496742 cites W2023827073 @default.
• W2318496742 cites W2030258959 @default.
• W2318496742 cites W2044268473 @default.
• W2318496742 cites W2056379862 @default.
• W2318496742 cites W2067373348 @default.
• W2318496742 cites W2071673425 @default.
• W2318496742 cites W2072194967 @default.
• W2318496742 cites W2073224590 @default.
• W2318496742 cites W2074962342 @default.
• W2318496742 cites W2078181283 @default.
• W2318496742 cites W2078830522 @default.
• W2318496742 cites W2079463138 @default.
• W2318496742 cites W2081676327 @default.
• W2318496742 cites W2091980159 @default.
• W2318496742 cites W2108559291 @default.
• W2318496742 cites W2115754685 @default.
• W2318496742 cites W2135497037 @default.
• W2318496742 cites W2142003905 @default.
• W2318496742 cites W2165826521 @default.
• W2318496742 doi "https://doi.org/10.1021/ic2016484" @default.
• W2318496742 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/22129042" @default.
• W2318496742 hasPublicationYear "2011" @default.
• W2318496742 type Work @default.
• W2318496742 sameAs 2318496742 @default.
• W2318496742 citedByCount "29" @default.
• W2318496742 countsByYear W23184967422013 @default.
• W2318496742 countsByYear W23184967422014 @default.
• W2318496742 countsByYear W23184967422015 @default.
• W2318496742 countsByYear W23184967422016 @default.
• W2318496742 countsByYear W23184967422017 @default.
• W2318496742 countsByYear W23184967422018 @default.
• W2318496742 countsByYear W23184967422019 @default.
• W2318496742 countsByYear W23184967422020 @default.
• W2318496742 countsByYear W23184967422021 @default.
• W2318496742 countsByYear W23184967422023 @default.
• W2318496742 crossrefType "journal-article" @default.
• W2318496742 hasAuthorship W2318496742A5010155058 @default.
• W2318496742 hasAuthorship W2318496742A5034447235 @default.
• W2318496742 hasAuthorship W2318496742A5045054303 @default.
• W2318496742 hasAuthorship W2318496742A5061347192 @default.
• W2318496742 hasConcept C116569031 @default.
• W2318496742 hasConcept C155647269 @default.
• W2318496742 hasConcept C161790260 @default.
• W2318496742 hasConcept C170493617 @default.
• W2318496742 hasConcept C178790620 @default.
• W2318496742 hasConcept C185592680 @default.
• W2318496742 hasConcept C188027245 @default.
• W2318496742 hasConcept C2776685382 @default.
• W2318496742 hasConcept C2778142098 @default.
• W2318496742 hasConcept C2778597550 @default.
• W2318496742 hasConcept C2780471494 @default.
• W2318496742 hasConcept C506065880 @default.
• W2318496742 hasConcept C55493867 @default.
• W2318496742 hasConcept C8010536 @default.
• W2318496742 hasConceptScore W2318496742C116569031 @default.
• W2318496742 hasConceptScore W2318496742C155647269 @default.
• W2318496742 hasConceptScore W2318496742C161790260 @default.
• W2318496742 hasConceptScore W2318496742C170493617 @default.
• W2318496742 hasConceptScore W2318496742C178790620 @default.
• W2318496742 hasConceptScore W2318496742C185592680 @default.
• W2318496742 hasConceptScore W2318496742C188027245 @default.
• W2318496742 hasConceptScore W2318496742C2776685382 @default.
• W2318496742 hasConceptScore W2318496742C2778142098 @default.
• W2318496742 hasConceptScore W2318496742C2778597550 @default.
• W2318496742 hasConceptScore W2318496742C2780471494 @default.
• W2318496742 hasConceptScore W2318496742C506065880 @default.
• W2318496742 hasConceptScore W2318496742C55493867 @default.
• W2318496742 hasConceptScore W2318496742C8010536 @default.
• W2318496742 hasIssue "1" @default.
• W2318496742 hasLocation W23184967421 @default.
• W2318496742 hasLocation W23184967422 @default.
• W2318496742 hasOpenAccess W2318496742 @default.
• W2318496742 hasPrimaryLocation W23184967421 @default.
• W2318496742 hasRelatedWork W2016099958 @default.
• W2318496742 hasRelatedWork W2041915051 @default.
• W2318496742 hasRelatedWork W2046820648 @default.

• next