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- W2318503339 abstract "Cross-linked epoxies prepared from diglycidyl ether of bisphenol A (DGEBA) exhibit substantial property differences due to isomeric structures of the diamine curatives, 3,3′- and 4,4′-diaminodiphenyl sulfone (DDS). Here, the motions of phenylene rings on both the bisphenol A (BPA) and DDS structures of the networks were investigated through solid-state NMR 2H line shape analysis to trace the molecular origins. Ring deuterated monomers, namely, DGEBA-d8, 33DDS-d8, and 44DDS-d8, were synthesized, and four deuterated networks were prepared. The line shapes of the ring motions were interpreted using a motional model that described both ring π-flips and main-chain fluctuations. The contributions of different ring motions to mechanical relaxations are elucidated, and the molecular origins of property differences are identified." @default.
- W2318503339 created "2016-06-24" @default.
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- W2318503339 date "2015-03-13" @default.
- W2318503339 modified "2023-10-18" @default.
- W2318503339 title "Phenylene Ring Motions in Isomeric Glassy Epoxy Networks and Their Contributions to Thermal and Mechanical Properties" @default.
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- W2318503339 doi "https://doi.org/10.1021/ma5022506" @default.
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