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- W231851054 abstract "Fumigants are used for control of nematodes, fungi, weeds, and insects in high-cash-value crops. Because of their high volatility, a large fraction of the applied mass may be volatilized from the soil surface following application. Emission reduction strategies are needed to prevent adverse human or environmental health impacts. Some emission-reduction strategies, such as tarping the soil surface with impermeable plastic, increase containment of fumigants in the soil. The resulting fumigant residues could cause atmospheric contamination once the tarp is disrupted, groundwater contamination if leaching is allowed, or phytotoxicity to the crop planted following fumigation. Previous research has shown that thiosulfate compounds, including ammonium thiosulfate (ATS), abiotically react with and detoxify halogenated fumigants in soil and water. In these experiments, we investigated subsurface application of ATS to reduce fumigant concentrations in the root zone, preventing off-site transport following fumigation. Results indicated that halogenated fumigants were dissipated more rapidly in soil receiving ATS application compared to those receiving water only. First-order dissipation half-lives were =1 day for the halogenated compounds 1,3-dichloropropene and propargyl bromide. For methyl isothiocyanate, a non-halog enated fumigant that does not undergo reaction with ATS, application of ATS had no impact on the rate of dissipation in soil. These results suggest that subsurface application of ATS may be useful for the root-zone remediation of halogenated compounds." @default.
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- W231851054 date "2003-07-23" @default.
- W231851054 modified "2023-10-14" @default.
- W231851054 title "Remediation of Halogenated Fumigant Compounds in the Root Zone by Subsurface Application of Ammonium Thiosulfate" @default.
- W231851054 doi "https://doi.org/10.1021/bk-2004-0863.ch013" @default.
- W231851054 hasPublicationYear "2003" @default.
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