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• W2318536428 endingPage "5907" @default.
• W2318536428 startingPage "5903" @default.
• W2318536428 abstract "A one-pot initiator-free Barton ester decomposition with tandem radical addition onto alkyl propiolates or phenylacetylene with aromatic substitution of the resultant vinyl radical allows convenient access to new 9-substituted 6,7-dihydropyrido[1,2-a]indoles. Propyl radical cyclizations compete when forming the expanded 7,8-dihydro-6H-azepino[1,2-a]indole system. 2-Thiopyridinyl S-radical is incorporated into aromatic adducts when using unsubstituted indole-1-alkanoic acid precursors. X-ray crystallography on substitution products allows selectivity of the radical addition onto less reactive internal alkynes to be determined." @default.
• W2318536428 created "2016-06-24" @default.
• W2318536428 creator A5017422174 @default.
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• W2318536428 date "2014-05-28" @default.
• W2318536428 modified "2023-09-30" @default.
• W2318536428 title "Tandem Reactions via Barton Esters with Intermolecular Addition and Vinyl Radical Substitution onto Indole" @default.
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• W2318536428 doi "https://doi.org/10.1021/jo5008543" @default.
• W2318536428 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/24837130" @default.
• W2318536428 hasPublicationYear "2014" @default.
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