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• W2318538049 abstract "Nanosecond laser flash photolysis employing transient detection of emission and absorption in combination with pulse radiolysis and quantum theory has been employed to shed light into the kinetics, quantum yields, and mechanisms of the deactivation of the first excited singlet state of 1- and 2-thionaphthols (NpSH(S(1))). In contrast to thiophenols (ArSH(S(1))), the results revealed that the decay of the first excited singlet state of 1- and 2-thionaphthols (NpSH(S(1))) is governed by radiationless internal conversion (Φ(IC) = 0.29-0.46; 0.016-0.190) and intersystem crossing (Φ(ISC) = 0.14-0.15; 0.4-0.6), respectively, with pronounced S-H photodissociation (Φ(D) = 0.40-0.55; 0.35-0.40). Fluorescence as a deactivation channel plays a minor role (Φ(F) = 0.001-0.010; 0.010-0.034). Quantum chemical calculations helped in understanding the formation of naphthylthiyl radicals and rationalizing the differences in the efficiency of intersystem crossing of the 1- and 2-thionaphthol systems." @default.
• W2318538049 created "2016-06-24" @default.
• W2318538049 creator A5005620103 @default.
• W2318538049 creator A5021022135 @default.
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• W2318538049 date "2010-12-30" @default.
• W2318538049 modified "2023-09-25" @default.
• W2318538049 title "Shedding Light into the Detailed Excited-State Relaxation Pathways and Reaction Mechanisms of Thionaphthol Isomers" @default.
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• W2318538049 doi "https://doi.org/10.1021/jp110701s" @default.
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• W2318538049 hasPublicationYear "2010" @default.
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