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• W2318542822 endingPage "3477" @default.
• W2318542822 startingPage "3474" @default.
• W2318542822 abstract "Lewis acid promoted substitution reactions employing Meldrum’s acid and 5-methyl Meldrum’s acid as carbon-based leaving groups are described which transform unstrained quaternary and tertiary benzylic Csp3–Csp3 bonds into Csp3–X bonds (X = C, H, N). Importantly, this reaction has a broad scope in terms of both suitable substrates and nucleophiles with good to excellent yields obtained (typically >90%)." @default.
• W2318542822 created "2016-06-24" @default.
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• W2318542822 creator A5044750583 @default.
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• W2318542822 creator A5073321347 @default.
• W2318542822 date "2012-06-14" @default.
• W2318542822 modified "2023-10-07" @default.
• W2318542822 title "Carbon-Based Leaving Group in Substitution Reactions: Functionalization of sp³-Hybridized Quaternary and Tertiary Benzylic Carbon Centers" @default.
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• W2318542822 doi "https://doi.org/10.1021/ol301442z" @default.
• W2318542822 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/22697467" @default.
• W2318542822 hasPublicationYear "2012" @default.
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