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- W2318557890 endingPage "1278" @default.
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- W2318557890 abstract "1,4-Diphenyl-1-telluro-1,3-butadiene incorporated in a dibenzobarrelene skeleton was synthesized with a good yield by an intramolecular Diels–Alder reaction of the corresponding 1-(9-anthyltelluro)enyne. Oxidation and bromination of the telluride yielded telluroxide and hypervalent Te,Te-dibromide, respectively. Their structures were determined by X-ray crystallography. Unlike its highly fluorescent sulfur and selenium congeners, the telluride is barely fluorescent in solution at room temperature due to the heavy-atom effect of tellurium. The telluride displayed temperature-dependent fluorescence; it is fluorescent with a moderate quantum yield (ΦPL = 0.42) in the glass of 2-methyltetrahydrofuran at 77 K." @default.
- W2318557890 created "2016-06-24" @default.
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- W2318557890 date "2015-03-26" @default.
- W2318557890 modified "2023-10-16" @default.
- W2318557890 title "Synthesis, Structures, and Temperature-Dependent Photoluminescence of 1,4-Diphenyl-1-telluro-1,3-butadiene Incorporated in a Dibenzobarrelene Skeleton and Derivatives" @default.
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- W2318557890 doi "https://doi.org/10.1021/acs.organomet.5b00016" @default.
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