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- W2318613758 abstract "A series of NaCa13/18Mg5/18PO4(NCMPO):A (A = Eu2+/Tb3+/Mn2+, Dy3+) phosphors have been prepared by the high-temperature solid-state reaction method. The X-ray diffraction (XRD) and Rietveld refinement, X-ray photoelectron spectroscopy (XPS), photoluminescence (PL), cathodoluminescence (CL), decay lifetimes, and PL quantum yields (QYs) were utilized to characterize the phosphors. The pure crystalline phase of as-prepared samples has been demonstrated via XRD measurement and Rietveld refinements. XPS reveals that the Eu2+/Tb3+/Mn2+ can be efficiently doped into the crystal lattice. NCMPO:Eu2+/Tb3+/Mn2+ phosphors can be effectively excited under UV radiation, which show tunable color from purple-blue to red including white emission based on energy transfer from Eu2+ to Tb3+/Mn2+ ions. Under low-voltage electron beam bombardment, the NCMPO:A (A = Eu2+/Tb3+/Mn2+, Dy3+) display their, respectively, characteristic emissions with different colors, and the CL spectrum of NCMPO:0.04Tb3+ has the comparable intensity to the ZnO:Zn commercial product. In addition, the calculated CIE coordinate of NCMPO:0.04Tb3+ (0.252, 0.432) is more saturated than it (0.195, 0.417). These results reveal that NCMPO:A (A = Eu2+/Tb3+/Mn2+, Dy3+) may be potential candidate phosphors for WLEDs and FEDs." @default.
- W2318613758 created "2016-06-24" @default.
- W2318613758 creator A5016367316 @default.
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- W2318613758 date "2014-11-06" @default.
- W2318613758 modified "2023-10-17" @default.
- W2318613758 title "Tunable-Color Luminescence via Energy Transfer in NaCa<sub>13/18</sub>Mg<sub>5/18</sub>PO<sub>4</sub>:A (A = Eu<sup>2+</sup>/Tb<sup>3+</sup>/Mn<sup>2+</sup>, Dy<sup>3+</sup>) Phosphors for Solid State Lighting" @default.
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- W2318613758 doi "https://doi.org/10.1021/ic502058r" @default.
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