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• W2318785845 abstract "Abstract In Diels-Alder additions of tetracyanoethylene to 1,2-, and 9-substituted anthracenes, formation constants (K) for the intermediate complexes have been separated from the global rate constant (k2obs). The relatively small range of values of K indicates a very small charge transfer in the complexes. The transition state for conversion of complex into adduct showed a marked degree of charge development, particularly for the 9-substituted derivatives (p = -7). Substituents in the outer rings gave good rate correlations with composite constants (σm++σp+) with a p value of - 3. The substituent effects are discussed in terms of these and other parameters. Values for equilibrium constants for the overall addition (Kcq) are reported." @default.
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• W2318785845 date "1981-01-01" @default.
• W2318785845 modified "2023-09-27" @default.
• W2318785845 title "Kinetics and mechanism of diels-alder additions of tetracyanoethylene to anthracene derivatives-III" @default.
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• W2318785845 doi "https://doi.org/10.1016/s0040-4020(01)98972-0" @default.
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