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• W2318821490 startingPage "6008" @default.
• W2318821490 abstract "Aryl alkynoate esters undergo gold-catalyzed spirocyclization under mild conditions, affording spirolactones in high yields. This approach obviates the need for stoichiometric halogenating reagents typically employed for alkyne activation in related transformations. Water was found to play a critical role in governing the product selectivity. Anhydrous conditions lead selectively to coumarin products, as has previously been observed for aryl alkynoate esters, while the addition of 1 equiv of water leads selectively to spirocycle formation." @default.
• W2318821490 created "2016-06-24" @default.
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• W2318821490 date "2014-11-03" @default.
• W2318821490 modified "2023-10-01" @default.
• W2318821490 title "Gold-Catalyzed Dearomative Spirocyclization of Aryl Alkynoate Esters" @default.
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• W2318821490 doi "https://doi.org/10.1021/ol503022h" @default.
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• W2318821490 hasPublicationYear "2014" @default.
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