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- W2318883916 abstract "A pulse radiolysis technique was used to study the ultraviolet absorption spectra of CCl3CClH and CCl3CClHO2 radicals, the kinetics of the self-reaction of CCl3CClHO2 radicals, and the kinetics of the reactions of CCl3CClHO2 with NO and NO2 in the gas phase at 296 K. At 240 nm, σ(CCl3CClH) = (303 ± 35) × 10-20, and at 250 nm, σ(CCl3CClHO2) = (288 ± 48) × 10-20 cm2 molecule-1. The observed rate constant for the self-reaction of CCl3CClHO2 radicals was (5.0 ± 1.2) × 10-12 cm3 molecule-1 s-1. The rate constants for reactions of CCl3CClHO2 radicals with NO and NO2 were k3 > 9.0 × 10-12 and k4 = (8.9 ± 2.6) × 10-12 cm3 molecule-1 s-1, respectively. A long path length Fourier transform infrared technique was used to show that at 295 K in 700 Torr total pressure of air 76 ± 3% of CCl3CClHO radicals decompose via C−C bond scission and 24 ± 3% undergo three-center intramolecular HCl elimination. As part of this work rate constants for the reaction of F and Cl atoms with CCl3CH2Cl were determined to be (6.4 ± 1.2) ..." @default.
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- W2318883916 date "1996-01-01" @default.
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- W2318883916 title "Atmospheric Chemistry of 1,1,1,2-Tetrachloroethane (CCl<sub>3</sub>CH<sub>2</sub>Cl): Spectrokinetic Investigation of the CCl<sub>3</sub>CClHO<sub>2</sub> Radical, Its Reactions with NO and NO<sub>2</sub>, and Atmospheric Fate of the CCl<sub>3</sub>CClHO Radical" @default.
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- W2318883916 doi "https://doi.org/10.1021/jp961489e" @default.
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