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• W2318899044 endingPage "616" @default.
• W2318899044 startingPage "608" @default.
• W2318899044 abstract "A new hydroxythiophenedicarboxylate metal–organic framework based on MnII cations has been obtained by an aqueous two-step procedure including hydrothermal treatment. The structure of Mn3(OH)2(C6H2O4S)2 has been determined ab initio from synchrotron X-ray powder diffraction data and consists of infinite inorganic ribbons which are interlinked by 2,5-thiophenedicarboxylate (tdc) molecules (monoclinic, space group P21/c, a = 3.4473(1) Å, b = 19.1287(1) Å, c = 11.0069(1) Å, β = 97.48(1)°, V = 719.65(1) Å3, and Z = 2). Each ribbon is built of three vertex-sharing chains of edge-sharing MnO6 octahedrons. These ribbons are bridged together by the carboxylate functions of the tdc molecule to form a pseudo-2D inorganic subnetwork, while this molecule develops in the third dimension to pillar these pseudo-2D layers. An unprecedented hexadentate symmetric bridging mode is adopted by tdc which bridges two chains of a ribbon on one side and two ribbons of a pseudo-2D inorganic subnetwork on the other side. Magnetic measurements suggest that the titled compound is antiferromagnetic below TN = 17.7 K. Heat capacity measurements confirm the existence of a magnetic phase transition toward a 3D long-range ordered state. These CP(T) data have also been used for the calculation of the thermal variations of both the adiabatic temperature change ΔTad and magnetic entropy change ΔSm of the material, namely its magnetocaloric effect." @default.
• W2318899044 created "2016-06-24" @default.
• W2318899044 creator A5043358986 @default.
• W2318899044 creator A5067953108 @default.
• W2318899044 creator A5077368028 @default.
• W2318899044 creator A5085338493 @default.
• W2318899044 creator A5088414847 @default.
• W2318899044 date "2012-12-28" @default.
• W2318899044 modified "2023-10-06" @default.
• W2318899044 title "Synthesis, Ab Initio X-ray Powder Diffraction Crystal Structure, and Magnetic Properties of Mn₃(OH)₂(C₆H₂O₄S)₂ Metal–Organic Framework" @default.
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• W2318899044 doi "https://doi.org/10.1021/ic301423c" @default.
• W2318899044 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/23273135" @default.
• W2318899044 hasPublicationYear "2012" @default.
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