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• W2318930721 abstract "[(C5Me5)LnMe2]3 (Ln = Y, Lu) dissolve readily in a n-hexane/toluene mixture upon addition of 3 equiv of the organoaluminum boryl compound [Me2Al{B(NDippCH)2}]2 (Dipp = C6H3iPr2-2,6). The half-sandwich complexes (C5Me5)Ln[(AlMe3){B(NDippCH)2}]2 thus formed display unsymmetrical heteroaluminate coordination not only in the solid state but also at lower temperatures in solution, which is distinct from the behavior of the homoaluminate congeners (C5Me5)Ln(AlMe4)2. The effect of homo- versus heteroaluminate coordination is assessed in the coordinative polymerization of isoprene." @default.
• W2318930721 created "2016-06-24" @default.
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• W2318930721 date "2014-03-19" @default.
• W2318930721 modified "2023-10-01" @default.
• W2318930721 title "Half-Sandwich Rare-Earth-Metal Alkylaluminate Complexes Bearing Peripheral Boryl Ligands" @default.
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• W2318930721 doi "https://doi.org/10.1021/om401163a" @default.
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