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- W2319061565 abstract "We report here the construction of quinolizidine ring systems by intramolecular cyclization of suitable functionalized piperidines via a reductive amination sequence. This reaction proceeds with a total stereocontrol at C4. The preparation of the piperidine precursors is based on a chain elongation of a piperidine aldehyde either by aldolization or by Wittig reaction. We applied this second route to the total synthesis of quinolizidine (−)-217A from (S)-methyl 2-((S)-1-((R)-1-phenylethyl)piperidin-2-yl)propanoate 5." @default.
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- W2319061565 date "2010-10-25" @default.
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- W2319061565 title "Total Synthesis of Quinolizidine (−)-217A" @default.
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- W2319061565 doi "https://doi.org/10.1021/jo101668k" @default.
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