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• W2319112640 endingPage "1470" @default.
• W2319112640 startingPage "1463" @default.
• W2319112640 abstract "A mild and highly stereoselective rhodium(II)-catalyzed cyclopropanation of alkenes, alkynes, and allenes with diacceptor diazo compounds is reported. Using the phosphonate moiety as an efficient trans-directing group, the first catalytic asymmetric route to diacceptor cycloprop(en)ylphosphonates was developed by employing an α-cyano diazophosphonate and Rh2(S-IBAZ)4 as chiral catalyst. The isosteric character of phosphonic and carboxylic acid derivatives allowed the alternative use of an α-cyano diazo ester in the process, leading to α-cyano cycloprop(en)ylcarboxylates in high yields and stereoselectivities. Taking advantage of the particular reactivity of the cyanocarbene intermediates involved in this system, the scope of compatible substrates could be extended to substituted allenes, leading to the development of the first catalytic enantioselective method for the synthesis of diacceptor alkylidenecyclopropanes." @default.
• W2319112640 created "2016-06-24" @default.
• W2319112640 creator A5000910820 @default.
• W2319112640 creator A5010065045 @default.
• W2319112640 creator A5015397332 @default.
• W2319112640 creator A5026261263 @default.
• W2319112640 creator A5052525748 @default.
• W2319112640 date "2013-01-15" @default.
• W2319112640 modified "2023-10-14" @default.
• W2319112640 title "Stereoselective Rh₂(<i>S</i>-IBAZ)₄-Catalyzed Cyclopropanation of Alkenes, Alkynes, and Allenes: Asymmetric Synthesis of Diacceptor Cyclopropylphosphonates and Alkylidenecyclopropanes" @default.
• W2319112640 cites W1933811786 @default.
• W2319112640 cites W1964109800 @default.
• W2319112640 cites W1964284609 @default.
• W2319112640 cites W1964801500 @default.
• W2319112640 cites W1967138415 @default.
• W2319112640 cites W1968888391 @default.
• W2319112640 cites W1969848498 @default.
• W2319112640 cites W1969943225 @default.
• W2319112640 cites W1970177290 @default.
• W2319112640 cites W1972071745 @default.
• W2319112640 cites W1972241043 @default.
• W2319112640 cites W1975804881 @default.
• W2319112640 cites W1976249706 @default.
• W2319112640 cites W1980368805 @default.
• W2319112640 cites W1983279529 @default.
• W2319112640 cites W1984823276 @default.
• W2319112640 cites W1985886364 @default.
• W2319112640 cites W1986472342 @default.
• W2319112640 cites W1986547861 @default.
• W2319112640 cites W1987595285 @default.
• W2319112640 cites W1988131389 @default.
• W2319112640 cites W1991470366 @default.
• W2319112640 cites W1991702876 @default.
• W2319112640 cites W1992585700 @default.
• W2319112640 cites W1997833502 @default.
• W2319112640 cites W1999030981 @default.
• W2319112640 cites W2001066055 @default.
• W2319112640 cites W2004100816 @default.
• W2319112640 cites W2004269581 @default.
• W2319112640 cites W2005399072 @default.
• W2319112640 cites W2006575732 @default.
• W2319112640 cites W2006664821 @default.
• W2319112640 cites W2008315207 @default.
• W2319112640 cites W2008881108 @default.
• W2319112640 cites W2010192832 @default.
• W2319112640 cites W2012140640 @default.
• W2319112640 cites W2014643313 @default.
• W2319112640 cites W2017807948 @default.
• W2319112640 cites W2018795945 @default.
• W2319112640 cites W2019648361 @default.
• W2319112640 cites W2019889862 @default.
• W2319112640 cites W2022913410 @default.
• W2319112640 cites W2023140410 @default.
• W2319112640 cites W2024874069 @default.
• W2319112640 cites W2028428446 @default.
• W2319112640 cites W2030108724 @default.
• W2319112640 cites W2033048991 @default.
• W2319112640 cites W2035228670 @default.
• W2319112640 cites W2038573548 @default.
• W2319112640 cites W2040041008 @default.
• W2319112640 cites W2045242294 @default.
• W2319112640 cites W2045603529 @default.
• W2319112640 cites W2049504060 @default.
• W2319112640 cites W2054024874 @default.
• W2319112640 cites W2067448802 @default.
• W2319112640 cites W2073341477 @default.
• W2319112640 cites W2075132137 @default.
• W2319112640 cites W2076318336 @default.
• W2319112640 cites W2077549261 @default.
• W2319112640 cites W2079812001 @default.
• W2319112640 cites W2079997911 @default.
• W2319112640 cites W2083672816 @default.
• W2319112640 cites W2084298631 @default.
• W2319112640 cites W2088943937 @default.
• W2319112640 cites W2089243275 @default.
• W2319112640 cites W2090554214 @default.
• W2319112640 cites W2091474437 @default.
• W2319112640 cites W2091800127 @default.
• W2319112640 cites W2091997636 @default.
• W2319112640 cites W2092456581 @default.
• W2319112640 cites W2098477058 @default.
• W2319112640 cites W2100082569 @default.
• W2319112640 cites W2106275240 @default.
• W2319112640 cites W2112685446 @default.
• W2319112640 cites W2119576339 @default.
• W2319112640 cites W2122383100 @default.
• W2319112640 cites W2127915043 @default.
• W2319112640 cites W2135681592 @default.
• W2319112640 cites W2140935725 @default.
• W2319112640 cites W2141951375 @default.
• W2319112640 cites W2147329676 @default.
• W2319112640 cites W2148192709 @default.
• W2319112640 cites W2149638826 @default.
• W2319112640 cites W2153045427 @default.
• W2319112640 cites W2154035508 @default.
• W2319112640 cites W2154747433 @default.
• W2319112640 cites W2154947949 @default.
• W2319112640 cites W2155353850 @default.

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