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- W2319275725 abstract "The B–S bond in N-heterocyclic carbene (NHC)–boryl sulfides can be cleaved homolytically to NHC–boryl or NHC–thioboryl and thiyl radicals using light, either directly around 300 nm or with a sensitizer at a longer wavelength (>340 nm). In contrast, the electrochemical reductive cleavage of the B–S bond is difficult. This easy photolytic cleavage makes the NHC–boryl sulfides good type I photopolymerization initiators for the polymerization of acrylates under air." @default.
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- W2319275725 date "2013-10-29" @default.
- W2319275725 modified "2023-09-30" @default.
- W2319275725 title "Formation of N-Heterocyclic Carbene–Boryl Radicals through Electrochemical and Photochemical Cleavage of the B–S bond in N-Heterocyclic Carbene–Boryl Sulfides" @default.
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- W2319275725 doi "https://doi.org/10.1021/ja4066267" @default.
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