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- W2319284705 abstract "Abstract Emulsion nanoparticles of polyaniline (PANI) were synthesized in the aqueous media by using hydroxylpropylcellulose (HPC) as a stabilizer and ammonium persulfate as an oxidant in the presence of TiO 2 with nanometer size. New poly(vinyl acetate) (PVAc) coating over carbon steel was prepared by addition of emulsion nanoparticles in different concentrations (1%, 2% and 1.5%) in PVAc as the major matrix. The Tafel plot records were used for the definition of potential and corrosion current (Icorr). Nanoparticles were characterized and compared by X-ray diffraction (XRD), thermal gravimetric analysis (TGA), Fourier transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM) and transmission electron microscopy (TEM). By adding TiO 2 , the thermal stability of the nanocomposite increased. A small size of colloidal particles prevented the precipitation of conducting polymer particles and led to better dispersion of nanocomposites in the matrix of the PVAc binder; therefore, the paint was homogeneous and anticorrosion properties of the coating increased. According to the results, 1.5% of PANI-TiO 2 nanocomposite in PVAc has a much lower Icorr in NaCl aqueous solution and 2% of PANI-TiO 2 nanocomposite in PVAc has the best corrosion protection in HCl." @default.
- W2319284705 created "2016-06-24" @default.
- W2319284705 creator A5007507727 @default.
- W2319284705 creator A5072811725 @default.
- W2319284705 date "2015-01-24" @default.
- W2319284705 modified "2023-10-18" @default.
- W2319284705 title "Preparation and characterization emulsion of PANI-TiO<sub>2</sub> nanocomposite and its application as anticorrosive coating" @default.
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- W2319284705 doi "https://doi.org/10.1515/polyeng-2014-0272" @default.
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