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• W2319310583 startingPage "2422" @default.
• W2319310583 abstract "The asymmetric total synthesis of the chlorinated [2.2.2]-diazabicyclic indole alkaloid (+)-malbrancheamide B is reported. Key to the synthesis is a domino reaction sequence that employs an aldol condensation, alkene isomerization, and intramolecular Diels–Alder cycloaddition. Diastereofacial selection between the azadiene stereofaces is enforced with a chiral aminal auxiliary. A formal 7-step (longest linear route) synthesis of (±)-malbrancheamide B is also reported." @default.
• W2319310583 created "2016-06-24" @default.
• W2319310583 creator A5072443012 @default.
• W2319310583 creator A5084590127 @default.
• W2319310583 date "2013-02-08" @default.
• W2319310583 modified "2023-10-10" @default.
• W2319310583 title "Enantioselective Synthesis of (+)-Malbrancheamide B" @default.
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• W2319310583 doi "https://doi.org/10.1021/jo3026059" @default.
• W2319310583 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/23360221" @default.
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