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• W2319312494 abstract "The photoionization mass spectra of toluene over the range 12 to 21 eV are contrasted with electron impact spectra over the same energy range. The experimental apparatus uses synchrotron radiation as the light source. The molecular ions from photon impact appear to have higher initial internal energy than those from electron impact at each energy studied. Evidence is presented that the molecular ion is vibrationally predissociated and that both types of spectra are in qualitative agreement with the quasi-equilibrium theory. However, evidence is also presented for a small contribution from a very fast, non-quasi-equilibrium process from the molecular ion paralleling the quasi-equilibrium process." @default.
• W2319312494 created "2016-06-24" @default.
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• W2319312494 date "1972-10-01" @default.
• W2319312494 modified "2023-10-17" @default.
• W2319312494 title "Photoionization mass spectrometry" @default.
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• W2319312494 doi "https://doi.org/10.1016/0020-7381(72)80031-7" @default.
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