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- W2319315512 abstract "Solid-state white-light emission was achieved from polystyrene (PS) microbeads incorporated with fluorophores based on perylene bisimide (PBITEG) and oligo(p-phenylenevinylene) (OPV) as acrylic cross-linkers. The PS beads incorporated with only PBITEG gave intense orange-red emission; PS incorporated with OPV exhibited blue-emission, whereas a series of polymers incorporating both cross-linkers exhibited varying shades of white-light emission. One of the PS samples, PS-PBITEG-6.25-OPV-4.28 (PBITEG incorporation: 6.25 × 10–7 mole; OPV incorporation: 4.28 × 10–7 mol), exhibited pure white-light emission in the powder form with CIE coordinates (0.33, 0.32). The rigid aromatic cross-linkers were incorporated into the PS backbone in a two-stage dispersion polymerization to afford PS beads in the size range 2 to 3 μm. The incorporation of fluorophores as cross-linkers enabled covalent attachment of the dye to the polymer backbone, avoiding dye leakage besides avoiding aggregation-induced fluorescence quenching." @default.
- W2319315512 created "2016-06-24" @default.
- W2319315512 creator A5020823011 @default.
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- W2319315512 date "2014-07-25" @default.
- W2319315512 modified "2023-10-04" @default.
- W2319315512 title "Blue, Green, and Orange-Red Emission from Polystyrene Microbeads for Solid-State White-Light and Multicolor Emission" @default.
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- W2319315512 doi "https://doi.org/10.1021/jp504718m" @default.
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