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• W2319316842 startingPage "3288" @default.
• W2319316842 abstract "Poly(phenylacetylene) (PPA) bearing dendritic oligo(ethylene glycol) (OEG) as pendants was synthesized, and its thermoresponsiveness and helical conformation were investigated. Despite the steric hindrance of the bulky pendants in the homopolymer PPA-OEG, the chirality could be efficiently transferred from pendant alanine moieties to PPA main chain through ester linkage. In order to examine the steric effect of pendants on chiral transformation, a model PPA homopolymer PPA-Boc which carries less bulky moieties was prepared for comparison. The chiroptical properties of these thermoresponsive PPAs were further investigated by varying temperature to examine the effects of their thermoresponsiveness. In addition, PPA copolymers PPA-BDY bearing OEG dendron and fluorescent boradiazaindacene (BDY) chromophore showed excellent thermoresponsive properties and interesting fluorescence enhancement at elevated temperatures. To investigate the rigidity effects of polymer backbone on the thermally induced fluorescence ..." @default.
• W2319316842 created "2016-06-24" @default.
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• W2319316842 date "2014-05-05" @default.
• W2319316842 modified "2023-10-14" @default.
• W2319316842 title "Thermoresponsive Helical Poly(phenylacetylene)s" @default.
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• W2319316842 doi "https://doi.org/10.1021/ma5003529" @default.
• W2319316842 hasPublicationYear "2014" @default.
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