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- W2319399653 abstract "INTRODUCTION The CIEEL (Chemically Initiated Electron Exchange Luminescence) mechanism has been utilized for the rationalization of a wide variety of bioluminescence and chemiluminescence (CL) processes,'*2 however, the efficiency for excited state formation of the originally studied CIEEL active systems has been questioned due to the re-determination of the quantum yields for the extensively studied diphenoyl peroxide system.' Although 172-dioxetanes containing simple alkyl and aryl substituents do not undergo catalyzed decomposition according to the CIEEL mechanism, 1,2-Dioxetane derivatives containing easily oxidizable substituents undergo fast decomposition, which is thought to be initiated by an intramolecular electron transfer from the electron-rich substituent to the peroxidic ring and leads to the efficient formation of singlet excited cleavage produck2 1,2-Dioxetanes containing protected electron-rich phenolate groups, which can by deprotected by the action of appropriate chemical or enzymatic trigger reagents, constitute the bases of several commercial immunoassay detection kits.' The induced decomposition of phenoxy-substituted 1,2-dioxetanes is initiated by an intramolecular electron transfer from the phenolate generated by the deprotecting reagent (fluoride in the case of silyl-protected phenolates) to the dioxetane ring, simultaneously with 0-0 bond cleavage (Fig. 1). 0 1" @default.
- W2319399653 created "2016-06-24" @default.
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- W2319399653 date "2007-07-01" @default.
- W2319399653 modified "2023-09-26" @default.
- W2319399653 title "EFFICIENCY OF ELECTRON-TRANSFER INDUCED CHEMIEXCITATION: A COMPARISON OF INTER- AND INTRAMOLECULAR PROCESSES" @default.
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- W2319399653 doi "https://doi.org/10.1142/9789812770196_0056" @default.
- W2319399653 hasPublicationYear "2007" @default.
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