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• W2319414196 endingPage "6723" @default.
• W2319414196 startingPage "6713" @default.
• W2319414196 abstract "The synthesis, structures and magnetic properties of a family of heterometallic [Mn(III)(5)Ln(III)(8)(mu(3)-OH)(12)(L(2))(4)(piv)(12)(NO(3))(4)(OAc)(4)](-) (Ln = Pr, 2; Nd, 3; Sm, 4; Gd, 5; Tb, 6) aggregates are reported. The complexes were obtained from the direct reaction of N-(t)butyldiethanolamine (H(2)L(2)) with Mn(OAc)(2) x 4 H(2)O and Ln(NO(3))(3) x 6 H(2)O in the presence of pivalic acid (pivH) in MeCN under ambient conditions. Compounds 2-6 are isomorphous and crystallize in the monoclinic space group P2(1)/n with four molecules in the unit cell. The complexes have a centrosymmetric tridecanuclear anionic core consisting of two distorted inner heterometallic [Mn(III)Ln(III)(3)(mu(3)-OH)(4)](8+) cubane subunits sharing a common Mn vertex flanked by four edge-sharing heterometallic [Mn(III)Ln(III)(2)(mu(3)-OH)(4)](5+) defect cubane units. Complexes 2-6 are the first high-nuclearity 3d-4f aggregates reported to date using (t)Bu-deaH(2) as ligand. These compounds show no evidence of slow relaxation behavior above 1.8 K, which appears to be the consequence of the very weak or non-existent magnetic interactions between the Mn(III) and Ln(III) ions resulting from the particular angles at the bridging oxygens." @default.
• W2319414196 created "2016-06-24" @default.
• W2319414196 creator A5016673925 @default.
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• W2319414196 creator A5087922259 @default.
• W2319414196 date "2009-06-16" @default.
• W2319414196 modified "2023-10-16" @default.
• W2319414196 title "Tridecanuclear [Mn^III₅Ln^III₈] Complexes Derived from <i>N</i>-^<i>t</i>Butyl-diethanolamine: Synthesis, Structures, and Magnetic Properties" @default.
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• W2319414196 doi "https://doi.org/10.1021/ic900645d" @default.
• W2319414196 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/19530694" @default.
• W2319414196 hasPublicationYear "2009" @default.
• W2319414196 type Work @default.

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