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- W2319548681 abstract "The design and assembly of new organophosphazene polymeric materials based on supramolecular “host–guest” interactions was accomplished by linkage of supramolecular coupling units to either the main-chain terminus or the side-chains of the parent phosphazene polymer. Noncovalent interactions at the main chain terminus were used to produce amphiphilic palm-tree like pseudoblock copolymers via host–guest interactions between an adamantane end-functionalized polyphosphazene and a 4-armed β-cyclodextrin (β-CD) initiated poly[poly(ethylene glycol) methyl ether methacylate] branched-star type polymer. Moreover, noncovalent interactions involving polymer side-chains were achieved between polyphosphazenes with β-CD pendant units and other polyphosphazene molecules with adamantyl moieties on the side-chains. These new organo–phosphazene structures based on noncovalent “host–guest” interactions generate new opportunities for the macromolecular modification of polyphosphazenes. The resultant materials demonstrated useful properties including self-aggregation, supramolecular gelation, and stimulus-responsive behavior." @default.
- W2319548681 created "2016-06-24" @default.
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- W2319548681 date "2014-02-03" @default.
- W2319548681 modified "2023-10-16" @default.
- W2319548681 title "Synthesis and Assembly of Novel Poly(organophosphazene) Structures Based on Noncovalent “Host–Guest” Inclusion Complexation" @default.
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- W2319548681 doi "https://doi.org/10.1021/ma500020p" @default.
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