Matches in SemOpenAlex for { <https://semopenalex.org/work/W2319686579> ?p ?o ?g. }
- W2319686579 endingPage "5288" @default.
- W2319686579 startingPage "5285" @default.
- W2319686579 abstract "NHC–gold(I) complexes promote carboxylative cyclization of a range of propargylic amines to afford (Z)-5-alkylidene-1,3-oxazolidin-2-ones in methanol under neutral and mild conditions. The highly active and robust catalyst permits CO2 utilization under a mixed gas atmosphere containing CO or H2. As a key intermediate, a new alkenylgold(I) complex was successfully identified from a stoichiometric reaction of Au(OH)(IPr) and 1-methylamino-2-butyne in THF. The methanol solvent influences the formation of catalytically active cationic gold species and facilitates protodeauration from the alkenylgold complex to release the cyclic urethane product due to in situ generation of methylcarbonic acid in the presence of CO2." @default.
- W2319686579 created "2016-06-24" @default.
- W2319686579 creator A5031109283 @default.
- W2319686579 creator A5090676837 @default.
- W2319686579 creator A5091894269 @default.
- W2319686579 date "2013-10-02" @default.
- W2319686579 modified "2023-10-16" @default.
- W2319686579 title "NHC–Gold(I) Complexes as Effective Catalysts for the Carboxylative Cyclization of Propargylamines with Carbon Dioxide" @default.
- W2319686579 cites W1972320122 @default.
- W2319686579 cites W1974353938 @default.
- W2319686579 cites W1981921235 @default.
- W2319686579 cites W1984023130 @default.
- W2319686579 cites W1993866658 @default.
- W2319686579 cites W1994567854 @default.
- W2319686579 cites W1996739334 @default.
- W2319686579 cites W1999694138 @default.
- W2319686579 cites W2011998601 @default.
- W2319686579 cites W2012395938 @default.
- W2319686579 cites W2019225864 @default.
- W2319686579 cites W2019659025 @default.
- W2319686579 cites W2021282327 @default.
- W2319686579 cites W2046199828 @default.
- W2319686579 cites W2054507307 @default.
- W2319686579 cites W2056390689 @default.
- W2319686579 cites W2056828245 @default.
- W2319686579 cites W2057419595 @default.
- W2319686579 cites W2057641806 @default.
- W2319686579 cites W2059290973 @default.
- W2319686579 cites W2059867752 @default.
- W2319686579 cites W2065620747 @default.
- W2319686579 cites W2066729344 @default.
- W2319686579 cites W2078795164 @default.
- W2319686579 cites W2082169127 @default.
- W2319686579 cites W2084235782 @default.
- W2319686579 cites W2086212483 @default.
- W2319686579 cites W2092022317 @default.
- W2319686579 cites W2094325514 @default.
- W2319686579 cites W2096042391 @default.
- W2319686579 cites W2105118416 @default.
- W2319686579 cites W2106715828 @default.
- W2319686579 cites W2113811322 @default.
- W2319686579 cites W2114082697 @default.
- W2319686579 cites W2134152609 @default.
- W2319686579 cites W2144350353 @default.
- W2319686579 cites W2151114296 @default.
- W2319686579 cites W2151593470 @default.
- W2319686579 cites W2152116424 @default.
- W2319686579 cites W2155111938 @default.
- W2319686579 cites W2158271313 @default.
- W2319686579 cites W2158815183 @default.
- W2319686579 cites W2163768766 @default.
- W2319686579 cites W2166675009 @default.
- W2319686579 cites W2170256944 @default.
- W2319686579 cites W2313784499 @default.
- W2319686579 cites W2316044755 @default.
- W2319686579 cites W2321291366 @default.
- W2319686579 cites W2330799344 @default.
- W2319686579 cites W2332399007 @default.
- W2319686579 cites W2333773087 @default.
- W2319686579 cites W2333791439 @default.
- W2319686579 cites W2485896866 @default.
- W2319686579 cites W2950650328 @default.
- W2319686579 cites W2950951276 @default.
- W2319686579 cites W2951446584 @default.
- W2319686579 cites W2952025026 @default.
- W2319686579 cites W2952182027 @default.
- W2319686579 cites W1998481454 @default.
- W2319686579 doi "https://doi.org/10.1021/om400949m" @default.
- W2319686579 hasPublicationYear "2013" @default.
- W2319686579 type Work @default.
- W2319686579 sameAs 2319686579 @default.
- W2319686579 citedByCount "109" @default.
- W2319686579 countsByYear W23196865792014 @default.
- W2319686579 countsByYear W23196865792015 @default.
- W2319686579 countsByYear W23196865792016 @default.
- W2319686579 countsByYear W23196865792017 @default.
- W2319686579 countsByYear W23196865792018 @default.
- W2319686579 countsByYear W23196865792019 @default.
- W2319686579 countsByYear W23196865792020 @default.
- W2319686579 countsByYear W23196865792021 @default.
- W2319686579 countsByYear W23196865792022 @default.
- W2319686579 countsByYear W23196865792023 @default.
- W2319686579 crossrefType "journal-article" @default.
- W2319686579 hasAuthorship W2319686579A5031109283 @default.
- W2319686579 hasAuthorship W2319686579A5090676837 @default.
- W2319686579 hasAuthorship W2319686579A5091894269 @default.
- W2319686579 hasConcept C161790260 @default.
- W2319686579 hasConcept C178790620 @default.
- W2319686579 hasConcept C185592680 @default.
- W2319686579 hasConcept C21951064 @default.
- W2319686579 hasConcept C530467964 @default.
- W2319686579 hasConceptScore W2319686579C161790260 @default.
- W2319686579 hasConceptScore W2319686579C178790620 @default.
- W2319686579 hasConceptScore W2319686579C185592680 @default.
- W2319686579 hasConceptScore W2319686579C21951064 @default.
- W2319686579 hasConceptScore W2319686579C530467964 @default.
- W2319686579 hasIssue "19" @default.
- W2319686579 hasLocation W23196865791 @default.