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• W2319706598 abstract "Thermal properties of channel water within crystalline nanopores of [M(H2bim)3](TMA)·nH2O (M = Co, Ru) were characterized by adiabatic calorimetry, where H2bim and TMA denote 2,2′-biimidazole and 1,3,5-benzenetricarboxylic acid, respectively. Temperature dependence of the heat capacities and spontaneous heat release or absorption rates disclosed the presence of two phase transitions and one glass transition at low temperatures in the both Co- and Ru-complex crystals. Combined with the results of M = Cr crystal, it was suggested that very slight differences in the pore size and shape strongly affect the phase behavior of the channel water. As the n value increases among the three crystals, the entropies of the channel water at 0 °C increased toward the value of pure water and the temperature dependence of the heat capacities around 0 °C seemed to somewhat resemble that of pure water as well. The glass transition was observed to occur at essentially the same temperature around 100 K among the three, indicating that the freezing-in rearrangement motion is related to breaking hydrogen bonds of the same number. The two phase transitions of the partially (88%) pore-filling water in the Ru-complex crystal occurred at appreciably lower temperatures than those of fully filling water. It is concluded that the ordering behavior of water molecules within nanopores with crystalline pore walls is sensitive to the pore structure, such as shape of the pore section and periodicity along the channel, and to the degree of pore filling with water." @default.
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• W2319706598 date "2012-05-21" @default.
• W2319706598 modified "2023-10-16" @default.
• W2319706598 title "Thermal Characteristics of Channel Water Confined in Nanopores with Crystalline Pore-Wall Structure in [M(H₂bim)₃](TMA)·<i>n</i>H₂O" @default.
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• W2319706598 doi "https://doi.org/10.1021/jp302222r" @default.
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