FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2319735549> ?p ?o ?g. }

• W2319735549 endingPage "5145" @default.
• W2319735549 startingPage "5135" @default.
• W2319735549 abstract "The sensitivity of electronic properties of organic conductors to minute modifications of their solid-state structure is investigated here within BEDT-TTF (ET) salts with organic bis-sulfonate anions, where specific hydrogen bonds between water molecules and sulfonate moieties are shown to dynamically control the organic slabs’ electronic structure. While the mixed-valence, 2,6-naphthalene-bis(sulfonate) salt, (ET)4(NBS)·4H2O, exhibits a charge order state already at room temperature, the corresponding salt with the 2,6-anthracene-bis(sulfonate) dianion, formulated as (ET)4(ABS)·4H2O, is metallic at RT and exhibits a metal–insulator transition at TMI = 85 K. The origin of the MI transition is revealed from a combination of temperature-dependent spectroscopic (Raman) measurements, X-ray structure elucidations (from 300 to 15 K), and theoretical investigations, demonstrating that the charge disproportionation observed below TMI is associated here with the progressive switching of bifurcated OH···O hydrogen bonds between the sulfonate moieties of the anion and the trapped water molecules. These movements within the anion layer are transmitted through weaker C–H···O interactions to the two A and B donor molecules, modifying the details of the overlap interactions within AA and BB pairs and opening a gap in the band structure." @default.
• W2319735549 created "2016-06-24" @default.
• W2319735549 creator A5001529398 @default.
• W2319735549 creator A5011223650 @default.
• W2319735549 creator A5029950669 @default.
• W2319735549 creator A5030432937 @default.
• W2319735549 creator A5032677000 @default.
• W2319735549 creator A5036244881 @default.
• W2319735549 creator A5039515913 @default.
• W2319735549 creator A5048552245 @default.
• W2319735549 creator A5057018652 @default.
• W2319735549 creator A5063749323 @default.
• W2319735549 creator A5066928337 @default.
• W2319735549 creator A5076043448 @default.
• W2319735549 creator A5086906829 @default.
• W2319735549 date "2013-10-18" @default.
• W2319735549 modified "2023-10-16" @default.
• W2319735549 title "Correlation between Metal–Insulator Transition and Hydrogen-Bonding Network in the Organic Metal δ-(BEDT-TTF)₄[2,6-Anthracene-bis(sulfonate)]·(H₂O)₄" @default.
• W2319735549 cites W180676439 @default.
• W2319735549 cites W1964824663 @default.
• W2319735549 cites W1969203784 @default.
• W2319735549 cites W1969635440 @default.
• W2319735549 cites W1969903890 @default.
• W2319735549 cites W1970824904 @default.
• W2319735549 cites W1971032360 @default.
• W2319735549 cites W1972669157 @default.
• W2319735549 cites W1976539920 @default.
• W2319735549 cites W1977512235 @default.
• W2319735549 cites W1977955686 @default.
• W2319735549 cites W1981244598 @default.
• W2319735549 cites W1981578297 @default.
• W2319735549 cites W1983510748 @default.
• W2319735549 cites W1984437904 @default.
• W2319735549 cites W1988594150 @default.
• W2319735549 cites W1988832693 @default.
• W2319735549 cites W1989969161 @default.
• W2319735549 cites W1996734750 @default.
• W2319735549 cites W1999456560 @default.
• W2319735549 cites W2003504678 @default.
• W2319735549 cites W2006990512 @default.
• W2319735549 cites W2008630708 @default.
• W2319735549 cites W2010820674 @default.
• W2319735549 cites W2014901786 @default.
• W2319735549 cites W2016774854 @default.
• W2319735549 cites W2019416707 @default.
• W2319735549 cites W2023904611 @default.
• W2319735549 cites W2025127524 @default.
• W2319735549 cites W2027795108 @default.
• W2319735549 cites W2030161200 @default.
• W2319735549 cites W2037714618 @default.
• W2319735549 cites W2038893442 @default.
• W2319735549 cites W2040168071 @default.
• W2319735549 cites W2043377731 @default.
• W2319735549 cites W2043819799 @default.
• W2319735549 cites W2048337574 @default.
• W2319735549 cites W2049058791 @default.
• W2319735549 cites W2053598517 @default.
• W2319735549 cites W2053985958 @default.
• W2319735549 cites W2054663635 @default.
• W2319735549 cites W2055816302 @default.
• W2319735549 cites W2060252775 @default.
• W2319735549 cites W2060964521 @default.
• W2319735549 cites W2063334178 @default.
• W2319735549 cites W2063481505 @default.
• W2319735549 cites W2063662678 @default.
• W2319735549 cites W2063970085 @default.
• W2319735549 cites W2074485872 @default.
• W2319735549 cites W2077888337 @default.
• W2319735549 cites W2080093295 @default.
• W2319735549 cites W2080310731 @default.
• W2319735549 cites W2082241723 @default.
• W2319735549 cites W2084835680 @default.
• W2319735549 cites W2088238123 @default.
• W2319735549 cites W2089038088 @default.
• W2319735549 cites W2091325798 @default.
• W2319735549 cites W2094539479 @default.
• W2319735549 cites W2101147669 @default.
• W2319735549 cites W2114290422 @default.
• W2319735549 cites W2139733952 @default.
• W2319735549 cites W2145349685 @default.
• W2319735549 cites W2146994780 @default.
• W2319735549 cites W2147619837 @default.
• W2319735549 cites W2155791473 @default.
• W2319735549 cites W2167849308 @default.
• W2319735549 cites W2313262047 @default.
• W2319735549 cites W2329713204 @default.
• W2319735549 cites W2330319263 @default.
• W2319735549 cites W2331007279 @default.
• W2319735549 cites W2950550425 @default.
• W2319735549 cites W2988810037 @default.
• W2319735549 cites W316801682 @default.
• W2319735549 cites W336196408 @default.
• W2319735549 cites W4236584863 @default.
• W2319735549 doi "https://doi.org/10.1021/cg401416h" @default.
• W2319735549 hasPublicationYear "2013" @default.
• W2319735549 type Work @default.
• W2319735549 sameAs 2319735549 @default.
• W2319735549 citedByCount "12" @default.

• next