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• W2319845817 abstract "The total synthesis of (±)-mevashuntin, a structurally unique naturally occurring pyrano-naphthoquinone-thiazolone, is described. The route is centered upon a late stage regioselective Diels–Alder reaction between two highly functionalized components, as well as an improved protocol for the one pot synthesis of benzothiazolones from ortho-bromoaryl isothiocyanates. The strategy results in a highly convergent route, providing access to the natural product in 11 steps from 3-(4-methoxyphenoxy)propanol and confirming its relative stereochemistry." @default.
• W2319845817 created "2016-06-24" @default.
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• W2319845817 date "2012-02-27" @default.
• W2319845817 modified "2023-09-24" @default.
• W2319845817 title "Total Synthesis of Mevashuntin" @default.
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• W2319845817 doi "https://doi.org/10.1021/ol300221e" @default.
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