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• W2319853428 endingPage "5035" @default.
• W2319853428 startingPage "5026" @default.
• W2319853428 abstract "The skeleton of the stemona alkaloid, stenine, has been synthesized starting from pyrrole, employing an asymmetric organocatalyzed cyclization, Sonogashira coupling, a diastereoselective intramolecular propargylic Barbier reaction, cyclocarbonylation, and diastereoselective alkene reduction. Modulation of the electron-rich nature of the pyrrole nucleus by employing an α-trifluoroacetyl group is essential. The α-trifluoroacetyl group may be rapidly removed under carefully defined, mild conditions." @default.
• W2319853428 created "2016-06-24" @default.
• W2319853428 creator A5031315667 @default.
• W2319853428 creator A5091797592 @default.
• W2319853428 date "2011-05-16" @default.
• W2319853428 modified "2023-10-01" @default.
• W2319853428 title "Synthesis of the Stenine Ring System from Pyrrole" @default.
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• W2319853428 doi "https://doi.org/10.1021/jo200699k" @default.
• W2319853428 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/21528882" @default.
• W2319853428 hasPublicationYear "2011" @default.
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