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- W2319896380 abstract "Thermoresponsive materials have overwhelming development prospects because of their excellent properties and widely potential applications. The polymer brushes of poly(MEO2MA- co -OEGMA526) were prepared by the copolymerization of 2-(2-methoxyethoxy)ethyl methacrylate (MEO2MA) and poly(oligo(ethylene glycol) methacrylate) (OEGMA526) on the gold surface of QCM chip via supramolecular self-assembled monolayers (SAM) and surface initiated polymerization (SIP). The thermoresponsive properties of polymer brushes were investigated by changing the solution concentration of initiator ( χ Isol), the molar concentration of monomer OEGMA526 ( C 526) and the dry film thickness ( d ). Studies via quartz crystal microbalance (QCM) showed that the lower critical solution temperature (LCST) of thermoresponsive polymer brushes poly(MEO2MA- co -OEGMA526) ( χ Isol = 1%; C 526 = 5%; LCST = 34 ℃) was mainly determined by the C 526 while the d almost had no effect. Terminal hydroxyl groups on thermoresponsive polymer brushes provided an opening for functional applications verified by the binding experiment of grafted biotin and streptavidin. Thermoresponsive and easily functional polymer brushes provide a new possibility for the development of novel temperature sensitive materials." @default.
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- W2319896380 date "2014-06-01" @default.
- W2319896380 modified "2023-10-16" @default.
- W2319896380 title "Preparation of thermoresponsive and easily functional polymer brushes and their thermoresponsive properties" @default.
- W2319896380 doi "https://doi.org/10.1360/n032014-00040" @default.
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