Matches in SemOpenAlex for { <https://semopenalex.org/work/W2319956028> ?p ?o ?g. }
Showing items 1 to 71 of
71
with 100 items per page.
- W2319956028 endingPage "C126" @default.
- W2319956028 startingPage "C126" @default.
- W2319956028 abstract "metal-organic frameworks (MOFs), however, the NTE mechanism in these structurally complicated compounds still eludes in-depth understanding. Here we use X-ray diffraction techniques to elucidate the nature of the isotropic NTE mechanism in the cubic metal-organic framework Zn4O(BDC)3 (BDC = benzenedicarboxylate), also known as MOF-5 or IRMOF-1. Variable temperature synchrotron radiation powder X-ray diffraction data reveal almost linear NTE behaviour in the measured temperature range from 80-500 K with α =dl/ldT=-11.2 ×10 K. Variable temperature single crystal X-ray diffraction (SCXRD) measurement over a broad temperature range has been used to probe the changes in atomic coordinates and vibrational modes causing the NTE behaviour in the framework. The results suggest population of transverse vibrations, similar to the findings in the metal cyanide frameworks [2], with preferential population of vibrational modes out-of-plane of the BDC oxygen atoms and of the BDC aromatic ring. [1] Evans, J. Chem. Soc., Dalton Trans. (1999) 3317 [2] Chapman et al., J. Am. Chem. Soc. (2005) 127, 15630" @default.
- W2319956028 created "2016-06-24" @default.
- W2319956028 creator A5085443214 @default.
- W2319956028 date "2008-08-23" @default.
- W2319956028 modified "2023-09-26" @default.
- W2319956028 title "Magnetic and crystal structure in connection with ferroelectric properties of multiferroic<i>R</i>Mn<sub>2</sub>O<sub>5</sub>" @default.
- W2319956028 doi "https://doi.org/10.1107/s0108767308095949" @default.
- W2319956028 hasPublicationYear "2008" @default.
- W2319956028 type Work @default.
- W2319956028 sameAs 2319956028 @default.
- W2319956028 citedByCount "0" @default.
- W2319956028 crossrefType "journal-article" @default.
- W2319956028 hasAuthorship W2319956028A5085443214 @default.
- W2319956028 hasBestOaLocation W23199560281 @default.
- W2319956028 hasConcept C115260700 @default.
- W2319956028 hasConcept C115624301 @default.
- W2319956028 hasConcept C121332964 @default.
- W2319956028 hasConcept C123266903 @default.
- W2319956028 hasConcept C133386390 @default.
- W2319956028 hasConcept C13355873 @default.
- W2319956028 hasConcept C175601593 @default.
- W2319956028 hasConcept C185592680 @default.
- W2319956028 hasConcept C192562407 @default.
- W2319956028 hasConcept C2524010 @default.
- W2319956028 hasConcept C26873012 @default.
- W2319956028 hasConcept C32546565 @default.
- W2319956028 hasConcept C33923547 @default.
- W2319956028 hasConcept C46141821 @default.
- W2319956028 hasConcept C49040817 @default.
- W2319956028 hasConcept C62520636 @default.
- W2319956028 hasConcept C79090758 @default.
- W2319956028 hasConcept C8010536 @default.
- W2319956028 hasConceptScore W2319956028C115260700 @default.
- W2319956028 hasConceptScore W2319956028C115624301 @default.
- W2319956028 hasConceptScore W2319956028C121332964 @default.
- W2319956028 hasConceptScore W2319956028C123266903 @default.
- W2319956028 hasConceptScore W2319956028C133386390 @default.
- W2319956028 hasConceptScore W2319956028C13355873 @default.
- W2319956028 hasConceptScore W2319956028C175601593 @default.
- W2319956028 hasConceptScore W2319956028C185592680 @default.
- W2319956028 hasConceptScore W2319956028C192562407 @default.
- W2319956028 hasConceptScore W2319956028C2524010 @default.
- W2319956028 hasConceptScore W2319956028C26873012 @default.
- W2319956028 hasConceptScore W2319956028C32546565 @default.
- W2319956028 hasConceptScore W2319956028C33923547 @default.
- W2319956028 hasConceptScore W2319956028C46141821 @default.
- W2319956028 hasConceptScore W2319956028C49040817 @default.
- W2319956028 hasConceptScore W2319956028C62520636 @default.
- W2319956028 hasConceptScore W2319956028C79090758 @default.
- W2319956028 hasConceptScore W2319956028C8010536 @default.
- W2319956028 hasIssue "a1" @default.
- W2319956028 hasLocation W23199560281 @default.
- W2319956028 hasOpenAccess W2319956028 @default.
- W2319956028 hasPrimaryLocation W23199560281 @default.
- W2319956028 hasRelatedWork W1677225103 @default.
- W2319956028 hasRelatedWork W1971880890 @default.
- W2319956028 hasRelatedWork W1975218798 @default.
- W2319956028 hasRelatedWork W2006273186 @default.
- W2319956028 hasRelatedWork W2017738234 @default.
- W2319956028 hasRelatedWork W2040974421 @default.
- W2319956028 hasRelatedWork W2085462595 @default.
- W2319956028 hasRelatedWork W2330257013 @default.
- W2319956028 hasRelatedWork W2560881082 @default.
- W2319956028 hasRelatedWork W2951886496 @default.
- W2319956028 hasVolume "64" @default.
- W2319956028 isParatext "false" @default.
- W2319956028 isRetracted "false" @default.
- W2319956028 magId "2319956028" @default.
- W2319956028 workType "article" @default.