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- W2320006810 abstract "We have synthesized a molecule containing a tight hydrogen-bonding interaction between an alcohol and a nonconjugated π-system. The strength of this hydrogen bond results in a large red shift, nearly 189 cm–1, on the alcohol stretching frequency in the IR spectrum in comparison to a free alcohol control. The interaction is notable in that it possesses a better defined intramolecular hydrogen bond compared to the usual molecules for which it is noted, such as syn-7-norbornenol. This interaction was studied through the use of IR and NMR spectroscopy, X-ray crystallography, and molecular modeling calculations." @default.
- W2320006810 created "2016-06-24" @default.
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- W2320006810 date "2015-04-14" @default.
- W2320006810 modified "2023-10-01" @default.
- W2320006810 title "Synthesis of a Tight Intramolecular OH···Olefin Interaction, Probed by IR, <sup>1</sup>H NMR, and Quantum Chemistry" @default.
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- W2320006810 doi "https://doi.org/10.1021/acs.joc.5b00470" @default.
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