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- W2320031182 abstract "In this work, Na3V2(PO4)2F3/C composite fluorophosphate cathode material is synthesized by a sol-gel process. The as prepared material shows excellent electrochemical performance. A capacity of 125 mAh/g of the material is obtained at the current density of 150 mA/g. When cycling at the current density of 3000 mA/g, it still delivers a capacity of 110 mAh/g (88% of the initial capacity at 150 mA/g). The charging and discharging mechanism of this material is investigated by synchrotron-based in situ XRD and ex situ MAS SS-NMR. In situ XRD results indicate a single phase electrochemical delithiation/lithiation process and the material shows excellent structure stability during charge/discharge process. The ex situ MAS SS-NMR results show that Li-Na exchange happens when Na3V2(PO4)2F3 contacts with electrolyte, and the charge/discharge mechanism is: Li+ and Na+ in the Na1 site are deintercalated from the structure in the first charge process; Li+ and Na+ are co-intercalated in the structure in the following discharge process." @default.
- W2320031182 created "2016-06-24" @default.
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- W2320031182 date "2012-01-01" @default.
- W2320031182 modified "2023-10-16" @default.
- W2320031182 title "<italic>In situ</italic> XRD and solid state NMR characterization of Na<sub>3</sub>V<sub>2</sub>(PO<sub>4</sub>)<sub>2</sub>F<sub>3</sub> as cathode material for lithium-ion batteries" @default.
- W2320031182 doi "https://doi.org/10.1360/032011-177" @default.
- W2320031182 hasPublicationYear "2012" @default.
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